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| HDPE | 日本聚烯烴 | HD KL471A |
PE最通常的生產方法是通過淤漿或氣相加工法,也有少數用溶液相加工生產。所有這些加工過程都是由乙烯單體、a-烯烴單體、催化劑體系(可能是不止一種化合物)和各種類型的烴類稀釋劑參與的放熱反應。氫氣和一些催化劑用來控制分子量。淤漿反應器一般為攪拌釜或是一種更常用的大型環形反應器,在其中料漿可以循環攪拌。當乙烯和共聚單體(根據需要)和催化劑一接觸,就會形成聚 乙烯顆粒。除去稀釋劑后,聚乙烯顆粒或粉粒被干燥并按劑量加入添加劑,就生產出粒料。帶有雙螺桿擠出機的大型反應器的現代化生產線,可每小時生產PE40000磅以上。新的催化劑的開發為改進新等級HDPE的性能作出貢獻。兩種最常用的催化劑種類是菲利浦的鉻氧化物為基礎的催化劑和鈦化合物一烷基鋁催化劑。菲利浦型催化劑生產的HDPE有 中寬度分子量分布;鈦一烷基鋁催化劑 生產的分子量分布窄。用復式反應器生產窄MDW的聚合物所用催化劑也可用 于生產寬MDW品級。舉例來說,生產顯著不同分子量產 品的兩個串聯反應器可以生產出雙峰分子量聚合物,這種聚合物具有全寬域的分子量分布。
Method for the production of PE is the most common by slurry or gas phase process, there are a few with solution phase processing. All of these processes are made of vinyl monomer, a- olefin monomer, catalyst system (may be more than one compound) exothermic reb and various types of hydrocarbon diluent participation. Hydrogen and catalyst is used to control the molecular weight. A slurry reactor is stirred tank or large loop reactor, a more common, in which the slurry can cycle stirred. When ethylene and a comonomer (as required) and catalyst contact, will b the polyethylene particles. After removal of the diluent, polyethylene particles or powder is dried and additive dosage, the production of pellets. Large reactor with double screw extruder production line, each hour pounds more than the PE40000 production. The development of new catalysts and contribute to the perbance improvement of the new class HDPE. Two kinds of catalyst is the most commonly used chrome oxide Philip based catalyst and titanium compound alkyl aluminium catalyst. Philip type catalyst for producing HDPE in b distribution of molecular weight; molecular weight titanium alkyl aluminium catalyst production of narrow distribution. With the production of narrow MDW complex reactor polymer catalyst can also be used in the production of wide MDW grade. For example, the production of different molecular mass production of two series reactor can produce Shuangfeng the polymer molecular weight, molecular weight distribution of the polymer has a full b domain.
| HDPE | 日本聚烯烴 | HD KL471A |
HDPE is a high degree of crystallinity, non-polar thermoplastic resin. The original state of HDPE milky white appearance, with a certain degree of translucent at thin section. PE has excellent chemical resistance properties with the most life and industry. Some kinds of chemicals will produce chemical corrosion, such as corrosive oxidizer (nitric acid) (Er Jiaben), aromatic hydrocarbons and halogenated hydrocarbons (carbon tetrachloride). The polymer is not hygroscopic and has good waterproof steam, and can be used for packing. HDPE has good electrical properties, especially the insulation of high dielectric strength, so it is suitable for wire and cable. Medium to high molecular weight grades with excellent impact resistance, at room temperature even in the -40F low temperature so. The unique characteristics of various grades of HDPE is an appropriate combination of four basic variables: density, molecular weight, molecular weight distribution and additive. Different catalysts are used in the production of customized special properties of polymer. These variables are combined to produce the different uses of HDPE grade; in the perbance of the best balance.
| HDPE | 日本聚烯烴 | HD KL471A |
The melting point of HDPE is 142 ℃, decomb temperature 300 ℃; the injection temperature adjustable interval larger. Injection molding, general use temperature is 180 ℃ --230 ℃; because the olefine plastic, it does not absorb water, production, without drying, but to the quality of the products, can be 60 ℃ drying 1hr, to discharge the water; the melt viscosity of polyethylene, flow length ratio is small, thin-walled products may lack of glue, therefore, gate and runner is relatively large; products easy with static electricity, surface easy to absorb. Shrinkage rate was 16 ‰; overflow boundary value for 0.05mm.
HDPE有數不清的應用,范圍從可重復使用的薄壁飲料杯到5-gsl罐,消費國內生產的HDPE的1/5。注塑品級一般熔體指數5~10,有具有韌性較低流動性品級和具有可加工性的較高流動性品級。用途包括日用品和食品薄壁包裝物;有韌性、耐用的食品和涂料罐;高抗環境應力開裂應用,如小型發動機燃料箱和90-gal垃圾罐。
一般的HDPE熔點為142℃,分解溫度為300℃;注塑溫度的可調區間較大。注塑時,一般使用溫度為180℃--230℃;因是烯烴類塑料,它不吸水,生產時,不需烘干,但為了產品質量,可用60℃溫度烘干1hr,以排出浮水;聚乙烯的熔體粘度大,流長比小,薄壁制品可能缺膠,因此,澆口和流道相對較大;制品易帶靜電,表面易吸埃。收縮率為16‰;溢邊值為0.05mm。
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本公司主要經營 :
通用塑膠:PP,ABS,HIPS,PE,EVA,PVC,GPPS;
工程塑膠:PMMA,PC,PA6,PC/ABS,PA66,PA4T,PA46,PA/ABS,PA/PPE,PA6T,PC/PBT,POM,PBT;
高溫塑膠:PPA,PA46,PA9T,LCP,PA6T;
特種工程塑膠:PPS,COC,COP,IXEF,PTFE,PFA,ETFE,FEP,PVDF,PEI,PEEK,PI,PPA,PES,PSU,PPSU,PSF,PUR,PA12,PA11


